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When Agent Phil Coulson's team of agents attacked a Centipede laboratory in Oakland, the dendrotoxin used in the Night-Night Pistol was ineffective when used on soldiers outfitted with multiple Centipede Devices such as Brian Hayward.
Leo Fitz and Jemma Simmons designed a special bracelet to inject a refined dose of the dendrotoxin directly into the port of the Centipede Device that is normally used to inject refills of the Centipede Serum.
While fighting a Centipede soldier in their Mojave Desert base, Agent Grant Ward confirmed his initial impression that the bracelet designed was not practical, so he extracted the dendrotoxin capsule from the bracelet and made the soldier swallow it.