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Odessa is a city in Ukraine.
In 2009, Natasha Romanoff was tasked with escorting a nuclear engineer out of Iran. Upon reaching the city of Odessa in Ukraine, they were attacked by the Winter Soldier, who made them lose control of their vehicle and fall off a cliff.
Romanoff managed to pulled the engineer and herself out, but the Winter Soldier, who was waiting for them, shot through Romanoff's stomach and killed the engineer.